原子荧光法测定水中汞的原子化条件研究

分别采用热原子化原子荧光法(热汞法)和冷原子化原子荧光法(冷汞法)测定水中汞,比较了两种方法的检出限、线性相关系数、准确度和精密度的差异。冷汞法和热汞法的检出限分别为0.003和0.01μg/L,标准曲线相关系数分别为0.999 9和0.999 7,加标回收率范围分别为102%~106%和106%~113%。结果表明,冷汞法比热汞法具有更低的检出限,灵敏度和准确度也略优于热汞法。对于冷汞法,提高负高压有利于提高方法的灵敏度、准确度,并具有更低的方法检出限。     

渗透法处理高盐废水的原理及工艺

高浓度含盐废水的主要处理方法有反渗透、离子交换、蒸馏等，目前处理成本比较高。为改变当前高盐废水处理成本居高不下的现状，受渗透的基本原理启发，以分析渗透法处理高盐废水的基本原理为基础，提出渗透法处理高盐废水的新工艺。以溶质氨的设计溶液为例，分析高盐废水处理的新工艺流程及工艺的可行性，井对比反渗透工艺，详细阐述新工艺的特点。经计算分析认为。基于渗透原理的高盐废水处理工艺可降低高盐废水的处理成本，可作为高含盐废水处理方法的一个新的研究方向。     

Influence of Al-oxide on pesticide sorption to woody biochars with different surface areas

Biochars’ properties will change after application in soil due to the interactions with soil constituents, which would then impact the performance of biochars as soil amendment. For a better understanding on these interactions, two woody biochars of different surface areas (SA) were physically treated with aluminum oxide (Al-oxide) to investigate its potential influence on biochars’ sorption property. Both the micropore area and mesopore (17～500 Å in diameter) area of the low-SA biochar were enhanced by at least 1.5 times after treatment with Al-oxide, whereas the same treatment did not change the surface characteristics of the high-SA biochar due partly to its well-developed porosity. The enhanced sorption of the pesticide isoproturon to the Al-oxide-treated low-SA biochar was observed and is positively related to the increased mesopore area. The desorption hysteresis of pesticide from the low-SA biochar was strengthened because of more pesticide molecules entrapped in the expanded pores by Al-oxide. However, no obvious change of pesticide sorption to the high-SA biochar after Al-oxide treatment was observed, corresponding to its unchanged porosity. The results suggest that the influence of Al-oxide on the biochars’ sorption property is dependent on their porosity. This study will provide valuable information on the use of biochars for reducing the bioavailability of pesticides.     

大学生就业难的原因分析及指导对策

本文对大学生就业存在的自身问题、高校办学专业设置和培养模式问题、用人单位的误区问题以及现今的社会问题等进行了理性分析，并提出了加强对大学生的就业指导，引导大学生树立科学理性的就业观，广泛疏通就业途径和集聚多方力量鼓励大学生自主创业的对策。     

崇明岛建设中的生态环境保护科技创新

崇明生态岛建设对科技创新的路径选择提出了很高的要求。崇明岛的生态科技创新，在解决资源、能源、环境等一系列与生态系统密切相关的问题中，发挥了重要的支撑和保障作用。在分析崇明生态岛建设过程中科技发展现状的基础上，提出了崇明生态岛建设中，利用科技创新规划生态建设和环境保护的思路：生态城镇的发展进程必须遵循生态学原则，重点发展低碳经济战略，节能减排，发展生态岛环境保护与资源循环利用技术体系。此外，还提出了崇明生态岛在新农村建设过程及生态文明建设中亟待解决的一些问题，进而使科技创新推动崇明岛生态建设的发展，实现人与自然的和谐。     

Application of CMB model for source apportionment of polycyclic aromatic hydrocarbons (PAHs) in coastal surface sediments from Rizhao offshore area, China

Polycyclic aromatic hydrocarbons (PAHs) in coastal surface sediments from Rizhao offshore area were analyzed by gas chromatography–mass spectrometry. A chemical mass balance (CMB) model developed by the U.S. Environmental Protection Agency (EPA), CMB8.2, was used to apportion sources of PAHs. Seven possible sources, including coal residential, coal power plant, diesel engines exhaust, gasoline engines exhaust, coke oven, diesel oil leaks, and wood burning, were chosen as the major contributors for PAHs in coastal surface sediments. To establish the fingerprints of the seven sources, source profiles were collected from literatures. After including degradation factors, the modified model results indicate that diesel oil leaks, diesel engines exhaust, and coal burning were the three major sources of PAHs. The source contributions estimated by the EPA’s CMB8.2 model were 9.25%, 15.05%, and 75.70% for diesel oil leaks, diesel engines exhaust, and coal burning, respectively.     

生态城市评价指标体系构建及实证研究

构建了针对秦皇岛市的生态城市评价指标体系,采用多指标综合评价法,对2011年秦皇岛市城市生态化程度进行了评价。结果表明:秦皇岛市城市生态化综合指数为0.687,生态化程度为2级水平,经济持续发展子系统和资源能源节约子系统较为薄弱。根据评价结果,提出了大力发展循环经济、加强水污染治理、提高资源能源利用效率、加大生态建设力度等建议。     

DDTC—TX—100胶束增溶直接光度法测定水中低含量铜

ＴｒｉｔｏｎＸ１００对ＤＤＴＣ（二乙基二硫代氨基甲酸钠）与铜反应生成的络合物Ｃｕ（ＤＤＴＣ）２有增溶增敏作用，建立了低含量铜直接光度测定法。操作简便快速，选择性、精密度和回收率均较好，相对标准偏差为０８％～４３％，回收率为９６％～１０６％，摩尔吸光系数ε＝６４×１０３Ｌ／（ｍｏｌ·ｃｍ     

用蒸压法制备新型粉煤灰水泥的研究

以粉煤灰、石灰为主要原料，经混合料制备、成型、蒸压、低温焙烧、粉磨工艺制备的新型水泥既具有普通水泥的胶凝特性，又同时具有水化热低、后期强度高的特点，对过程工艺参数、物料配比对新型水泥的质量影响进行了研究，该工艺有望为粉煤灰在水泥行业的规模化利用提供技术支持。